Nanjing Liwei Chemical Co., Ltd

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Polyaluminium Chloride: A Commentary on Its History, Properties, and Impact

Historical Development

Polyaluminium chloride isn't a new player in water treatment, but its journey from humble coagulant to a staple in municipal and industrial use deserves a spotlight. As early as the mid-20th century, researchers noticed that throwing plain alum into waterways caused all kinds of issues — aluminum sulfate released too much sludge, and water tasted a bit off. Chemists in Japan and Europe found they could alter the process, reacting aluminum hydroxide with hydrochloric acid and drum up a more efficient, cleaner coagulant. Over decades, as countries set tougher drinking water standards, demand for something better than liquid alum rose sharply. At treatment plants in the late 1970s, the first big switch happened. Clearer water, faster settling — people on both sides of the tap could tell. Today, cities in every corner of the world depend on this chemical, and the way we talk about modern water safety owes much to those early tweaks on aluminum chemistry.

Product Overview

In its current forms, polyaluminium chloride comes as a yellowish powder or liquid, both aimed at binding up dirt and organic gunk in water. Supplying engineers count on its stability during storage, its ability to handle a wider pH range than old-school alum, and its knack for cutting down filter backwashing cycles. Companies sell it not just by basic purity or color but by polymerization and basicity levels, which blend into differences in charge and reactivity. Municipal and industrial buyers pick specific blends, sometimes blended with a dash of iron salt or silica, to tackle everything from river sediment to textile runoff. With so much of our planet facing water quality crises, people in the field appreciate something that performs well even when incoming water changes day to day.

Physical & Chemical Properties

What stands out about polyaluminium chloride is how the mix of aluminum polymers behaves. Out of the bag or tank, it's caked up or syrupy, with a sharp, slightly acidic tang. The powder clumps if you leave it open, so workers take care sealing it after use. As for chemistry, its aluminum content can vary, but hovers in the 28–32% range. It dissolves fast and produces a positively charged solution, which helps it latch onto negatively charged particles and pull them out of suspension. The high charge density compared to alum means it needs a lighter dose for the same cleaning punch. It performs best in water temperatures above freezing, though modern formulations stretch the boundaries in colder climates.

Technical Specifications & Labeling

In manufacturing and trade, polyaluminium chloride’s quality matters more than just the name on the barrel. Detailed labeling points to aluminum oxide content, basicity (which is a measure of how much acid has been neutralized), acidity, and iron impurities. Buyers demand batch certifications proving these numbers, since small shifts can mean clogs in plant filters or subpar water clarity. Some market standards also list particle size, residual monomer content, and pH values for a 1% solution. Countries like China and India, running mega-scale water plants, enforce strict codes here — it’s not unusual for shipments to get turned away at borders over tiny deviations on these labels.

Preparation Method

Factories don’t just dump ingredients in a pot — producing polyaluminium chloride means tightly controlled mixing, heating, and polymerization. The usual process runs aluminum hydroxide through a reaction with hydrochloric acid under precise temperature and mixing regimes. Some manufacturers use aluminum bauxite or recycled aluminum scrap as a feed, partly to lower costs and partly to cut waste. As water is added, chains of aluminum-oxygen-chloride form and tangle up, producing those long polymers that define the product’s action. Some production lines go a step further, adding in modifier ions or running the reaction in reactors lined to prevent contamination. The final product is dried and milled for powder, or pumped straight into drums as liquid.

Chemical Reactions & Modifications

Once inside a water treatment plant, polyaluminium chloride gets a new job. Dosed into raw water, its aluminum polymers start hunting for negatively charged colloids and natural organic matter. These ions latch on, stick together, and punch out of suspension as fluffy flakes, or “floc.” Operators have learned to fine-tune this reaction by changing dose, pH, and even adding a polyacrylamide flocculant. Not every application works with the same mix — for tough wastewater streams, plants tweak the polymerization level or add sulfate to form polyaluminium chlorosulfate, which carries more punch against dyes and heavy metals. Every tweak in the recipe produces a ripple through floc size, settling time, and finished water quality.

Synonyms & Product Names

Polyaluminium chloride wears a lot of hats in the commercial world. In order sheets and import logs, it pops up as PAC, polyaluminum chloride, polymere aluminum chloride, or even just “yellow alum.” Some producers list it by molecular ratios, like PAC 30 or PAC 23, which point to aluminum content. Specialty blends—especially in pulp and paper and mining—carry trade names from their chemical houses, but inside a plant, just about everyone calls it “PAC.” The growth of international trade in water chemicals means buyers need to double-check the labels, especially on bulk shipments from overseas, where labeling conventions change.

Safety & Operational Standards

Working with any powdered chemical takes training and respect, and PAC is no exception. It doesn’t give off noxious fumes, but it is acidic and can irritate skin or lungs during handling. Facilities enforce protective protocols: gloves, eye protection, and respirators during big mixing jobs. Keeping dust out of eyes and lungs matters as much as keeping powder out of the water system’s intake channels. Spills need to get swept up fast because once wet, PAC solidifies and gums up grates or pipes. Storage demands dry, cool conditions, with tightly sealed drums or silo tanks. International bodies like ISO and ASTM publish handling standards, and I remember the relief on a supervisor’s face once after a new automated feeding system reduced operator contact. Every improvement in safety not only prevents injuries, but also guarantees the consistency water treatment depends on.

Application Area

From my time in municipal projects to consulting for textile discharge plants, PAC keeps turning up as the unglamorous hero. Drinking water plants in Asia, Europe, and the Americas pick it for its cost-to-clear ratio. Factory managers dealing with inky, dye-stained wastewater lean on high-polymer products, since they bind up color and complex organics better than alum. In pulp and paper, operators use PAC to catch fibers and reduce chemical oxygen demand. Even swimming pools and cooling towers use tailored doses to keep water sparkling. Agriculture, too, sources it to treat runoff before discharge. The ability to customize dose and blend means the same shipment might end up treating city water today and tackling mining tailings tomorrow.

Research & Development

PAC’s long track record hasn't stopped researchers in universities or corporate labs from experimenting for better results. Over the last decade, the focus has shifted from saving dose costs to cutting residual aluminum in finished water and boosting performance in cold climates. Green chemistry is making inroads — scientists test ways to use waste acids from other industries or lower-energy reaction paths in manufacturing. Some work focuses on blending PAC with bio-based flocculants, seeking to minimize any ecological aftertaste. The drive to improve doesn’t just live in labs; operators in plants often run dockside trials, sending samples through jar tests and tweaking settings day by day. In my limited role in a lab, I saw how small changes in basicity, even just a percentage point, could mean the difference between a routine day and a flood of customer complaints. It’s an area where both basic science and practical trial-and-error matter.

Toxicity Research

Public concern about aluminum compounds isn’t unjustified. Research teams worldwide have examined risks of long-term aluminum buildup in water, possible neurotoxic effects, and environmental impact from PAC byproducts. Regulatory agencies cap allowable aluminum in drinking water—usually under 0.2 mg/L in finished supply—to head off any risks. Studies keep reassessing the fate of PAC breakdown products, tracking whether residues slip past plant filters or accumulate in soil after sludge spreading. Most field data show that, when handled well, PAC puts less residual aluminum in water than traditional alum. Toxicologists test its effect on fish and plankton, with mixed findings depending on local water chemistry. In a community outreach session I attended, plant operators reassured local groups by showing independent tests of finished water, which built trust and kept everyone alert to best practices.

Future Prospects

Looking ahead, PAC stands at a crossroads. Climate instability, aging water infrastructure, and tighter standards for micro-pollutants all push the field. Chemists continue searching for ways to make PAC from recycled aluminum scraps, and use greener acids to drive the reactions. In water-stressed regions, the drive to purify lower-quality sources demands new, robust versions of PAC that can handle high organics, low temperatures, and complex industrial byproducts. Digital controls and sensor feedback at treatment plants unlock further efficiency, dialing in feed rates to cut waste and avoid overdosing. On the horizon, new research into combined coagulant systems and hybrid polymer blends could cut the total chemical load. As communities everywhere wake up to the realities of water scarcity and safety, PAC’s story remains unfinished — but its record so far points to many more chapters ahead.



What is Polyaluminium Chloride used for?

Polyaluminium Chloride: Making Water Safer

Folks in my hometown rarely thought about what happens after turning on the tap. The water just flows, cold and clear. Dig a little deeper, and it becomes clear that keeping that water safe takes real work. Polyaluminium chloride, or PAC, is one of the chemicals folks rely on to keep drinking water free from dangerous stuff.

PAC acts as a coagulant. That means it helps gather up tiny particles floating in the water—things like dirt, bacteria, viruses, and even heavy metals. Those particles carry health risks, especially for the youngest and oldest among us. Drop some PAC into a treatment tank, give it a whirl, and the particles start sticking together. The clumps, called flocs, grow heavy and settle out of the water. This step goes a long way toward cleaning up water that would otherwise be unsafe to drink.

Why Water Utilities Trust PAC

Not all coagulants work the same way. Alum, the old standby, comes with drawbacks—mainly, it needs more chemicals to balance the pH after treatment, and it produces more sludge. PAC outdoes alum by working at a wider pH range and cutting down on the sludge often dumped in landfills. Less sludge means lower disposal costs and less environmental mess.

Research backs up PAC's safety and performance. The World Health Organization mentions PAC as a dependable water treatment chemical. Tests from real-world plants regularly show lower levels of dangerous microbes and less cloudiness in finished water.

PAC Beyond Drinking Water

Ask around at a paper mill or textile factory, and PAC comes up in another way. These industries use lots of water, then release it back into rivers or city treatment systems. Regulations demand cleaner discharge water, and fines hit hard if companies fail to deliver. Factories add PAC to their water to catch color, fibers, or oils before sending it down the pipe. Municipal sewage plants lean on PAC for much the same reason—without it, the sewer effluent runs dirtier and risks hurting ecosystems.

Pool operators and even some farmers turn to PAC. In parks, PAC clears up fountains and ponds after storms wash in mud and organic debris. Runoff from farms or construction sites ends up in local waterways, carrying fertilizers and other pollution. By treating water with PAC before it flows downstream, communities can head off algae blooms and fish kills.

Concerns, Oversight, and Smarter Use

No chemical comes without trade-offs. Overusing PAC leaves behind aluminum residue. High aluminum in drinking water links to risks for kidneys, especially among people with certain health conditions. Regulators keep strict limits on aluminum content, and water plants test often to stay safe.

PAC doesn’t fix every water problem. Some pollutants, like dissolved salts or pharmaceuticals, slip past standard treatment. That highlights why towns still need multiple steps for water safety, including filtration, disinfection, and sometimes advanced approaches like activated carbon.

Looking ahead, water safety will always need a balance between affordability, effectiveness, and health. Folks who run the plants must keep up with new research and adapt their methods. PAC earns its spot because it brings results, but ongoing oversight and fresh solutions matter if our water is going to stay clean and safe.

Is Polyaluminium Chloride safe for drinking water treatment?

What Is Polyaluminium Chloride?

Polyaluminium chloride, usually shortened to PAC, ends up in a lot of water treatment plants around the world. It acts as a coagulant, which means it grabs onto tiny bits in the water and helps them clump together. Most water treatment plants face a constant battle with cloudy, dirty water. With so many moving parts, every step needs to work properly, or you’ll end up with a glass nobody wants to drink. That’s where PAC comes in. This powder or liquid makes dirt and other particles stick together, so filters can grab them. 

For years, I’ve paid attention to reports from the World Health Organization and local municipal plants working to keep families safe. They keep a close eye on PAC’s impact. The need for clean, safe water sits behind every decision made in a city treatment lab.

How Safe Is PAC in Drinking Water?

PAC’s safety record draws from dozens of studies and decades of hands-on use. The US Environmental Protection Agency, the World Health Organization, and national bodies like India’s Bureau of Indian Standards monitor its application. If PAC is mixed in at the right dose and the treated water gets filtered thoroughly, the leftover aluminum in the water stays well below the thresholds that might affect health. For those concerned about aluminum, the key questions point to the amount that actually ends up in a glass at the kitchen sink.

Most experts agree that aluminum intake from water remains small compared to diet. Leafy vegetables, cereals, and even tea bring in more aluminum each day than properly treated water. The WHO set a guideline of 0.2 mg/liter aluminum in finished water. If a water plant keeps their filters tidy and doesn’t overfeed the PAC, the water meets this mark every time.

Health scares usually come from plants that skip maintenance or add much more coagulant than necessary. That’s happened a few times in the past, with problems popping up in small towns rather than major cities. Routine testing stops mistakes before they spread.

Concerns and Alternatives

Residents sometimes worry about long-term risks, especially for people with kidney disease or babies. This isn’t paranoia. Some research in the 1990s asked if aluminum might link to Alzheimer’s, but so far large studies haven’t backed up those fears at the levels seen in safe drinking water. To stay transparent, treatment plants post their testing numbers, so anybody can check for themselves.

Alternatives do exist. Alum used to be the go-to, but it leaves more leftover aluminum than PAC. Some places look at natural coagulants from seeds or plant extracts. These new ideas sound attractive, but often can’t scale up to clean millions of gallons per day without raising costs or letting bugs sneak through the cracks.

What Can Be Improved?

Safe water goes beyond just picking the right chemical. Maintenance crews need training, water labs must stay funded, and the public deserves honest talk about water quality. If you drink city tap water, your health depends on the people running those tests. Strict rules, better equipment, and regular audits can catch errors before anyone gets sick.

From what I’ve seen, sticking with a proven coagulant like PAC, keeping dosing in check, and making results public keeps confidence high. None of this replaces long-term investment in better pipes, smarter sensors, and treating staff like the professionals they are.

PAC in drinking water isn’t perfect, but safe use rests on good oversight, honest data, and care for the health of every household.

What is the recommended dosage of Polyaluminium Chloride?

The Role of Polyaluminium Chloride in Water Treatment

Polyaluminium chloride, or PAC for short, finds its way into drinking water, industrial wastewater, and even swimming pools, helping clear out particles and bacteria. Anyone who’s had to rely on tap water knows how important it is to keep things safe and germ-free. PAC steps in as a coagulant, pulling together the unwanted stuff so it can get filtered out. It’s stronger than old-fashioned alum in many cases, and it doesn’t leave as much sludge behind.

Recommended Dosage: There’s No One-Size-Fits-All

From city engineers to folks running factories, the most common question about PAC is, “How much should we use?” In most cases, dosages typically land between 10 mg/L and 50 mg/L for drinking water. Some sources recommend higher amounts if water is especially dirty, or if there’s a lot of organic material floating around. In wastewater settings—say a textile plant or food factory—doses might reach 50 mg/L up to 300 mg/L depending on the mess.

Lab testing is key. Water might look clean, but invisible stuff like natural organic matter or heavy metals can throw things off. Experienced operators don’t just rely on numbers from a book. They run “jar tests”—mixing different amounts of PAC with a water sample and seeing what works best. It’s a hands-on process that lets treatment plants get good results without overdoing it.

Why Overdosing is a Problem

Using too much PAC wastes money, and it can cause problems for the filters, pipes, or the environment downstream. Extra chemicals may react with leftover organic matter, leading to by-products that aren’t good for health. The US Environmental Protection Agency and European regulators keep a close watch for that very reason.

One thing I’ve seen in real-world water labs: folks who try to “play it safe” by pouring in extra coagulant often end up with cloudy water or a ton of leftover sludge. That only adds to disposal costs—and sometimes complaints from people using the water. It’s always easier to make small adjustments than to fix an overloaded system.

Quality and Safety First

Not all PAC is created equal. Impurities, pH, and even the color of the powder or solution matter. High-quality suppliers provide detailed certificates and technical data, so treatment operators know exactly what’s in each drum. Reputable plants check batch quality against international standards, like NSF/ANSI 60 in the United States, making sure every gram goes a long way, not just into the drain.

Safety for workers matters too. Even experienced operators wear gloves and eye protection, since PAC can cause irritation if mishandled. Companies train their teams on storage and dosing equipment to reduce the risk of spills. From my own days in an industrial lab, confusion usually comes from skipping training or relying on guesswork instead of careful measurement.

Taking Responsibility: Smarter Use of PAC

Every gram of PAC added to water serves a purpose: clearer water, safer communities, fewer germs. Knowing the recommended range—10 to 50 mg/L for tap water, up to 300 mg/L for tougher jobs—is only one step. Real-world experience, testing, and respect for both budgets and safety make all the difference. Smarter chemical use helps the environment and saves money. Trust the data, train people well, and never ignore what the tests say.

How should Polyaluminium Chloride be stored?

Why Proper Storage Matters

Polyaluminium chloride (PAC) powers everything from clean drinking water to safer swimming pools. People rely on its strong ability to clump together nasties and make water clearer. Still, I’ve seen too many companies stack bags anywhere there’s space or leave barrels out back. Aside from losing out on quality, nobody wants unknown chemicals leaking or mixing with food or farm supplies just because the last delivery sat near the fertilizer. There’s a reason seasoned plant managers pay attention to these details—poor storage can cause health hazards, damage equipment, and waste money, fast.

Moisture: The Enemy Nobody Talks About

PAC hates water before it meets a treatment tank. I’ve watched pallets of product turn into sticky messes after a humid week. Moisture sneaks in through broken packaging or condensation, creating lumps that won’t dissolve right or feed into dosing systems. Dry, cool rooms mean less product loss. For operations running close margins, even a small percentage wasted hurts the bottom line. Run a dehumidifier if your storage space feels clammy, and keep everything off the floor with raised pallets.

Avoiding Problematic Reactions

Mixing chemicals can go wrong even in small quantities. I’ve never forgotten the time a delivery guy left PAC next to a barrel of chlorine—close call. Exposure to acids, strong oxidizers, or bases might trigger nasty reactions. Keep PAC away from all other chemicals, especially anything that could give off fumes or heat. Separate rooms go a long way, but if that’s impossible, use sturdy partitions and don’t rely on hope.

Keeping the Package Intact

Bagged PAC and liquid drums both need some care. Torn packaging spills fine dust or corrosive liquid. Anyone who’s cleaned that up knows it’s both a health problem and a money drain. Insist on inspecting deliveries for holes or leaks. Seal up any tears right away or transfer the material to sound containers.

Suppliers sometimes cut corners on packaging quality. Look for tough liners and rigid plastic drums that don’t turn soft in the sun. Keep containers closed tight—humidity, bugs, and contamination travel fast.

Temperature: Out of the Sun, Out of Trouble

Direct sunlight and heat break down PAC faster than most folks realize. You open a bag after two months in a sunny shed and it already clumps or smells wrong. Aim for shaded, cool storage. Indoor spaces with steady temperatures keep both liquid and powder stable longer. High heat increases the chance for gases to build up in closed containers, and that can mean a messy surprise. Store PAC away from machinery that throws off heat or from direct southern windows.

Protecting the Crew

People handling PAC deserve better than old gloves or dusty masks. Fine particles irritate skin and lungs, making daily handling a risk. Invest in chemical-resistant gloves, goggles, and dust masks for anyone moving or measuring product. Good signage lowers the chance of someone reaching into the wrong drum. Even the cleanest warehouse needs quick access to eye-wash stations and showers in case of accidents.

Earning Trust Through Careful Practice

Whether running a community utility or supplying a small hotel, how you store chemicals builds your reputation. Regulatory audits, customer trust, and team safety all depend on these habits. Smart managers look at storage as a type of insurance. Simple steps—keep it dry, cool, intact, and away from trouble—protect both people and business. No shortcuts last long in the chemical world.

What are the differences between yellow and white Polyaluminium Chloride?

Why Color Tells a Bigger Story

Anyone working around water treatment or industrial processing probably knows about Polyaluminium Chloride (PAC). These familiar yellow or white powders have become mainstays in clarifying water and cleaning up wastewater. But too often, the focus stays on technical specs, missing the real-world decisions folks make every day: do you buy the yellow stuff or the white?

Breakdown of Raw Materials and Purity Levels

The color difference starts with raw materials. Yellow PAC uses low-iron or even recycled aluminum sources, so minerals and metals linger. This tint signals higher iron content, but also means a more affordable product. White PAC takes a different path—producers go after pure alumina, plus stricter filtration. That bleached-out look isn’t just for show; it means fewer impurities and more controlled composition.

In my experience at a mid-size treatment plant, the purchasing team looked at budgets and water targets. For river water with all kinds of sediment and organic stuff, yellow PAC did the trick and saved money. For food or hospital use—where trace metals can’t sneak through—white PAC made the arguments for itself.

Effectiveness Across Different Waters

Yellow PAC sees a lot of use for good reason. It packs a punch for turbid or polluted waters, where heavy-duty flocculation is the name of the game. You find it poured at city water plants, in textile factories, or at pulp and paper mills. Its effectiveness comes from doing the basics right: it binds well with dirt, plant matter, even some industrial residues. The bonus? It comes at a lower cost, easing pressure on tight municipal budgets.

White PAC shines in specialty settings. Without the extra metals, this grade stays neutral and clean—perfect for treating water headed into pharmaceuticals, beverages, or electronics plants. Pure water keeps chemicals safe and taste untainted. If you’ve ever tasted cola off a bottling line, white PAC probably played a part behind the scenes. From time to time, stricter government regulations force a shift from yellow to white, since downstream processes demand ever-lower contamination.

Environmental and Health Factors

No one wants public health on the line because of cheap coagulants. Both yellow and white PAC break down pretty safely in most water bodies, but residual aluminum content stays a concern. Too much leftover aluminum in drinking water can build up, hitting folks with kidney trouble or young children hardest. Studies referenced by the World Health Organization highlight this risk, especially where quality control slips.

Environmental labs I’ve worked with run tighter checks before approving white PAC for food or pharmaceutical lines, screening every shipment for trace metals. Workers handling these powders should wear protective equipment—aluminum dust isn’t something anyone wants in their lungs. Adding more robust safety and supply chain management will help keep hidden hazards from slipping through.

Weighing Cost Against Quality

At the end of the day, budget almost always drives the bus. Yellow PAC usually clocks in at a lower price per ton, letting city councils stretch their funds and reach more people. White PAC costs more but delivers extra peace of mind, especially for high-stakes applications. Forward-thinking water utilities work directly with suppliers for better quality control, using batch testing and independent verification before chemicals even reach a reservoir.

For both types, tracking down a reliable supplier and keeping close tabs on chemical analysis reports matters more than the color alone. Knowing your water’s starting point and final use sets the whole game plan. Even as technology improves, these basics remain true in almost every treatment facility around the world.

Polyaluminium Chloride
Polyaluminium Chloride
Names
Preferred IUPAC name Aluminium chlorohydrate
Other names PAC
Poly Aluminium Chloride
Polyaluminum Chloride
Aluminium Chlorohydrate
Aluminum Polychloride
PACL
Aluminium Hydroxychloride
Pronunciation /ˌpɒli.əˈluːmɪniəm ˈklɔːraɪd/
Identifiers
CAS Number 1327-41-9
Beilstein Reference 35654
ChEBI CHEBI:88221
ChEMBL CHEMBL1201780
ChemSpider 23497
DrugBank DB11093
ECHA InfoCard 03d226e9-e938-4497-97c2-46488e2c9cbe
EC Number 1327-41-9
Gmelin Reference 37368
KEGG C18661
MeSH D000925
PubChem CID 10176869
RTECS number ST8220000
UNII O45QXMK83W
UN number UN3264
Properties
Chemical formula AlnCl(3n-m)(OH)m
Molar mass AlₙCl₍₃ₙ₋ₘ₎(OH)ₘ, variable
Appearance Light yellow powder
Odor Odorless
Density 1.15-1.20 g/cm3
Solubility in water Easily soluble in water
log P -2.28
Vapor pressure Negligible.
Acidity (pKa) 8.5-10.0
Basicity (pKb) 7.0 – 9.0
Magnetic susceptibility (χ) Diamagnetic
Refractive index (nD) 1.500
Viscosity 10-30 mPa·s
Dipole moment 0 D
Pharmacology
ATC code V07AB
Hazards
Main hazards Corrosive, causes severe skin burns and eye damage, harmful if swallowed or inhaled, may cause respiratory irritation.
GHS labelling GHS07, GHS05
Pictograms 'GHS05,GHS07'
Signal word Warning
Hazard statements H318: Causes serious eye damage.
Precautionary statements P260, P264, P280, P301+P312, P305+P351+P338, P330, P337+P313
NFPA 704 (fire diamond) Health: 2, Flammability: 0, Instability: 1, Special: -
Lethal dose or concentration LD50 Oral - Rat - **1,950 mg/kg**
LD50 (median dose) LD50 (oral, rat): 1,950 mg/kg
NIOSH SDZ3675000
PEL (Permissible) 10 mg/m³
REL (Recommended) 30 mg/L
IDLH (Immediate danger) Not established
Related compounds
Related compounds Aluminium chlorohydrate
Aluminium sulfate
Ferric chloride