Nanjing Liwei Chemical Co., Ltd

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Cuprous Iodide: A Close Look at a Versatile Inorganic Compound

Historical Development

Cuprous iodide, known chemically as CuI, caught the interest of chemists back in the early nineteenth century. They first prepared it during experiments with copper salts and various halogens. People soon realized that this simple compound blends deep chemical intrigue with real-world use. Early researchers like Sir Humphry Davy and Jöns Jacob Berzelius uncovered fundamental reactions, setting the scene for the compound to feature in countless laboratories and industries. Over decades, shifting demand from photographic plates to electronic components nudged scientists to keep searching for better synthesis routes and broader applications.

Product Overview

This white or off-white powder stands out for its robust chemical stability and relatively straightforward handling. Chemists see it as much more than a minor laboratory reagent. Cuprous iodide lands in several practical fields, from catalysts for pharmaceuticals to cloud-seeding agents in weather modification. Even now, it sits confidently in catalogs for educational, industrial, and research supply chains, supporting teaching labs and commercial users alike. Under the hood, its value comes from being reliable, relatively non-hygroscopic, and easy to store under standard dry conditions.

Physical & Chemical Properties

Cuprous iodide brings a unique set of properties. It usually appears as a pale white crystalline solid but sometimes looks reddish because of slight oxidation or exposure to air. It melts at about 605°C and doesn’t dissolve in water, which keeps it stable in many environmental conditions. Its cubic zinc blende structure allows consistent interaction in catalysis and electronics. While it resists many common acids, exposure to oxidizing agents or ammonia can shift its structure and chemistry. In my own undergraduate experiments, its stubborn insolubility made certain filtrations drag on, but that same property also protected it from degradation.

Technical Specifications & Labeling

Industry suppliers identify cuprous iodide by parameters like purity (often ≥99%), particle size, and trace metal content. It usually comes labeled with its CAS number (7681-65-4), UN number, and hazard identifiers. In labs, these specifics matter because trace contamination can derail sensitive experiments, especially in organometallic synthesis. Sometimes lot certificates detail spectroscopic profiles or the results of thermogravimetric analysis. In my work, I always checked these values closely, because getting the wrong form or a contaminated batch can waste both raw materials and precious time.

Preparation Method

You can synthesize CuI by several routes, but the classic approach dissolves copper sulfate in water, adds iodide ions (often from potassium iodide), and stirs in a reducing agent to ensure copper stays in the +1 oxidation state. The bright white precipitate that forms proves the reaction’s gone well. On an industrial scale, processes become more complex, often tailoring temperature and pH and recirculating filtrate to optimize economies of scale. Once isolated, product quality hinges on careful washing and drying to avoid surface oxidation—a task that laboratory chemists, including myself, watch closely. Even a hint of ammonia in the air can affect the final structure.

Chemical Reactions & Modifications

Cuprous iodide doesn’t just act like a spectator; it gets involved in key synthetic steps. In organic reactions like the Sandmeyer reaction, it helps convert aromatic amines into aryl iodides. It serves as a mild catalyst for coupling reactions, adding value in pharmaceutical and fine chemical synthesis. In my lab classes, we saw it help forge carbon-nitrogen bonds more efficiently than copper sulfate. It can form complexes with phosphines, cyanides, and halides, expanding its utility. In atmospheric science, its relatively inert behavior matches safety needs, letting technicians disperse it for cloud nucleation without rapid decomposition.

Synonyms & Product Names

This compound shows up with several names, including cuprous iodide, copper(I) iodide, and in older texts, “copper monoiodide.” Some trade names reflect specific formulations or purities—like “Cubiod” for high-purity technical grades. Recognizing synonyms helps avoid confusion, especially when ordering for projects that need strict material verification. Having worked with legacy protocols, I’ve seen the value of cross-referencing chemical synonyms to avoid the slow frustration of mismatched stock or misallocated budget.

Safety & Operational Standards

Handling cuprous iodide rarely feels risky in a modern lab, but good habits keep people safe. Powders can cause temporary irritation on contact or inhalation, so gloves and masks help. Storage in airtight containers minimises moisture uptake and limits accidental formation of copper(II) species, which pose more significant toxicity risk. Regulatory bodies such as OSHA and REACH set the limits on exposure and transportation. In industrial plants, teams follow protocols for dust containment and proper labeling. From my experience, even experienced chemists stick to standard operating procedures—especially since cumulative exposure to heavy metals, even in mild forms, adds up over decades.

Application Area

Many sectors benefit from this compound. Pharmaceutical chemists value it for catalyzing carbon-nitrogen and carbon-oxygen coupling, helping to build complex molecules. Electronics manufacturers use it in thin films and semiconductors, drawn by its useful electrical properties and relative abundance. In agriculture, it once helped to tackle fungal infections, though more targeted fungicides now dominate. Meteorologists release fine particles from aircraft to seed clouds, aiming to boost rainfall or manage drought conditions. I’ve seen its versatility spark new ideas in research grant proposals—few inorganic chemicals play a role from the classroom to the upper atmosphere.

Research & Development

Fresh developments continue to push cuprous iodide’s boundaries. Teams around the world keep refining catalysts to enhance performance and selectivity. Advances in semiconductor research increasingly turn to CuI for transparent electronic devices, OLEDs, and batteries. Recent projects explore hybrid copper halides for flexible displays and improved solar panels. Researchers also look for new ways to recycle copper and iodine from spent catalysts, aiming to cut costs and address sustainability concerns. Close collaboration between universities and industries quickens the pace—a dynamic I’ve seen pay off in the form of patents and published breakthroughs within just a few years.

Toxicity Research

Most studies agree that cuprous iodide’s toxicity sits at the lower end for copper compounds—though ingestion or long-term inhalation still brings health risks. The copper ion can disrupt cellular metabolism, especially in aquatic environments, leading to bioaccumulation or toxicity for fish and invertebrates. Iodide ions typically pose little hazard at low concentrations, but high doses stress thyroid function. Well-controlled toxicity studies guide regulatory limits and disposal practices. Environmental chemists track leaching and runoff, developing safe containment protocols, and pushing for remediation technologies to recover both copper and iodine from waste streams. Experience teaches that safety training and environmental mindfulness keep both people and ecosystems protected.

Future Prospects

The search for sustainable technology and novel chemistry keeps cuprous iodide in sharp focus. As demand for transparent, flexible electronics grows, CuI’s optical and electrical traits could pave the way for new sensors and smart windows. Cleaner synthetic methodologies and green chemistry initiatives pressure manufacturers to develop less wasteful production cycles, creating both challenges and opportunity. Resource recovery—especially copper and iodine extraction from used devices—may open new business models. I expect regulatory scrutiny and competition with greener alternatives to sharpen innovation, rather than slow it. People researching battery technologies, data storage, and photonics already use this compound’s charm to spin up ideas that wouldn’t have seemed possible a generation ago.



What is Cuprous Iodide used for?

What Cuprous Iodide Does in the Real World

Cuprous iodide pops up in more places than most people expect. Behind that chemical name sits a white or tan powder, easy to overlook, though its uses stretch from industry to medicine. My first brush with it came during a visit to a ceramics studio, where I watched a glazer mix chemicals, including copper compounds, to produce distinct colors. Those compounds slide their way into dozens of other corners of everyday life—not just art studios.

Making Electronics and Tech Work

Some folks know copper for its electricity-conducting skills. What’s less obvious: cuprous iodide delivers key benefits in electronics manufacturing. In the world of semiconductors, this powder can act as a hole transport layer and sometimes helps make light-emitting diodes (LEDs) last longer. The need for resilience in electronics pushes researchers to test countless compounds. Independent studies point out cuprous iodide’s stability and compatibility. University research papers have credited it for improving device efficiency. Consumer electronics companies keep digging deeper into these copper-based materials to produce devices that stand up to drops and heat. That saves people from dealing with broken screens or failing parts.

Moderator in Medicine and Nutrition

Taking in enough iodine can mean the difference between good thyroid health and years of health hassles. Table salt gets “iodized” for this reason. Food scientists and nutrition specialists have turned to cuprous iodide as a way to give salt a safe, stable source of iodine. The United States Food and Drug Administration lists it as an approved additive for salt fortification. Without such fortification, regions far from the sea could face stubborn public health problems. My grandmother grew up in an area with low soil iodine—doctors saw kids with goiters all the time until iodization spread. Cuprous iodide offers a clear solution: it resists clumping and reacts less strongly with moisture, keeping salt free-flowing and effective.

Fighting Fungi and Protecting Crops

Agriculture brings its own set of challenges as pests and diseases threaten food supply. Cuprous iodide enters the story as a fungicide. It disrupts fungal growth on crops, helping producers keep yields up without turning to heavier chemicals. The rise of resistance to common pesticides invites continued experimentation. Recent research from agricultural departments highlights the value in using copper compounds with a more targeted approach, reducing environmental impact while keeping food affordable. Farmers still debate the best mix, but cuprous iodide has shown results against stubborn blights, especially for fruit and vegetable growers.

Industrial Strength and Lasting Power

Corrosion pits bridges, ships, and buildings against the elements. In paints and coatings, cuprous iodide serves as an additive to block rust and marine growth. Paint crews demand products that hold up against saltwater spray and heavy rain. Adding this copper salt to marine paints deters barnacles and extends maintenance windows, keeping ships out of dry dock and on the move. Shipyard workers—a group often ignored in chemical debates—have long vouched for paints rich in copper salts, saying the difference is obvious during hull inspections.

Staying Mindful of Environmental Impact

It’s tough to overlook that increased use of metal compounds brings important questions about runoff, soil health, and long-term effects. Regulatory bodies like the Environmental Protection Agency weigh toxicity risks with benefits in food safety and infrastructure. Sustainable farming practices call for careful tracking, not just swapping one chemical for another, and it’s up to chemical manufacturers and regulators to stay vigilant. From my experience volunteering in community gardens, conversations about copper-based sprays always circle back to balance: protect plants, but don’t damage soil microbes or water supplies.

Is Cuprous Iodide safe to handle?

Understanding Cuprous Iodide

Cuprous iodide pops up in labs, industry, and sometimes even health supplements. Its pale color makes it look harmless, but there’s always more to the story with chemical powders. Some folks use it in advanced electronics, others experiment with it in chemical syntheses, and a few companies use it for its nutritional iodine. But the big question stays the same: can you safely handle it?

What Science Says About Safety

Direct contact with cuprous iodide irritates skin, eyes, and the lungs. During my years working in a college chemistry lab, powdered chemicals like this demanded careful handling. Even with gloves and goggles, I always felt a bit uneasy—not from visible reactions but from breathing in fine dusts during spills or cleanup. OSHA lists this compound as an irritant for a reason. One minor spill and you learn quickly how a dry cough or skin itch can ruin a workday.

Eating this stuff on purpose is a bad idea. Ingested copper salts (including this one) can create headaches, nausea, or worse, depending on how much gets in your system. Iodide brings its own risks, especially to people with thyroid problems, so even small supplement doses need strong regulation oversight. Many “natural” iodine blends claim to use safe amounts, but ingredient slip-ups do happen. For folks who think chemicals outside the lab always mean danger, that’s an exaggeration, but there’s truth behind the caution.

Environmental Side Effects

Sloppy handling of cuprous iodide adds copper and iodide into wastewater. Both elements affect aquatic systems. I’ve visited labs and factories where unsealed containers leave dust settling on the floor or washing down drains. Fish and insects suffer from too much copper—essential for life, but only in tiny traces. Regulators like the EPA set strict discharge rules for heavy metals due to these kinds of unintended leaks.

Making Workplaces Safer

The basics still work well: use gloves, eye protection, and lab coats. Open it only under a fume hood, not on open benches. Respirators matter if the job kicks up a lot of dust. After several cases of rashes and allergies among my lab mates, our supervisor switched everyone to disposable coveralls for big transfers. Training helps too, not just once when you’re hired, but every year or so, since habits fade. Units with strong safety records keep staff in the loop about near-misses or new procedures.

For companies adding cuprous iodide to supplements, food production lines must account for possible spills, scale residue, or airborne powders. Automatic feeders and closed systems keep exposure close to zero in large plants. Audits and third-party testing set a solid standard for consumer protection, and it makes a difference.

Looking to the Future

Nobody needs to panic, but respect for chemicals goes a long way. Safer substitutions and smarter packaging will help. Feeding direct experience into workplace training, sharing stories about accidents, and listening when workers speak up all matter just as much as regulations. If a chemical like cuprous iodide slips past the radar, the blame lands on more than one desk. It takes ongoing effort—not just a safety label—to truly protect health.

What is the chemical formula of Cuprous Iodide?

The Formula: CuI—A Tiny Concept, Big Role

Cuprous iodide shows up in textbooks and laboratories with a simple chemical shorthand: CuI. Behind these two letters, though, lies a story about how chemistry builds the materials we handle every day. Coming across this formula reminds me of countless afternoons in the chemistry lab, mixing reagents, recording changes, and always being amazed at how predictable patterns lead to specific compounds. Seeing CuI is more than just reading “copper” married to “iodine”—it’s witnessing a perfect match from the periodic table.

Digging Into the Meaning

Chemical formulas like CuI aren’t just neat—they also clue us into how elements interact. Here, copper takes its +1 oxidation state, so “cuprous” really does mean copper is sharing exactly one positive charge. Iodide fills the charge gap with a negative one. They pair up in a ratio of 1:1. It’s a simple partnership at the atomic level. I remember how professors would stress these relationships in class, using salt-like CuI to illustrate how metals and nonmetals combine. You see it in real life—CuI creates a white, powdery substance, unlike so many more vibrant copper compounds.

Importance Beyond the Lab

The reach of Cuprous iodide goes way beyond academic curiosity. It shows up in weather modification, as a nucleating agent that helps clouds form rain. I’ve read about how, during drought seasons, scientists seed clouds with CuI to coax them into rainfall, a science-based version of hoping for better weather. In organic synthesis, chemists turn to CuI for making complex, carbon-based products. Inside electronics, CuI helps craft high-purity crystals for detectors and semiconductors. All of this stems from understanding that simple 1-to-1 ratio. Knowing formulas like CuI makes a difference in innovation, from getting better crops in dry lands to smarter sensors in our smartphones.

Safety, Supply, and Environmental Concerns

Learning about compounds in a textbook is one thing; handling them responsibly is another. Cuprous iodide’s low toxicity doesn’t mean it’s harmless. During my time in research, I always watched for safe storage and disposal—chemicals don’t just vanish down the drain. Production standards must stay high so contamination doesn’t ride along with each shipment. Environmental exposure can lead to accumulation in soil or water, and while CuI breaks down slowly, every lab and factory plays a role in keeping those releases to a minimum.

Fostering Smarter Use and Innovation

It surprised me how old practices with CuI (and other inorganic salts) still pop up. Some industries keep using outdated processes or skipping modern monitoring tools. There’s room for improvement—stricter handling, more research on eco-friendly disposal, and better education for anyone who works with or around copper compounds. Welcoming technology also means getting better at tracking where chemicals go after they’ve been used. Our health, food supply, and electronics benefit from these efforts. Across science, industry, and policy, understanding formulas like CuI promises smarter solutions for future challenges.

How should Cuprous Iodide be stored?

Why Good Storage Matters

Cuprous iodide doesn’t look all that threatening at first glance—a white or off-white powder, fairly unassuming. Dig a little deeper into its chemistry, though, and it becomes clear that proper storage isn’t just a technical recommendation. It keeps the material useful, protects health, and makes sure no one ends up footing the bill for waste or safety accidents.

Moisture Control Isn’t Optional

Cuprous iodide picks up moisture from the air. Even on a shelf in a dry room, it can turn clumpy or discolor. Once water mixes in, that stable white powder turns into something unpredictable. I’ve seen small labs forced to toss out entire batches because someone left containers slightly open, thinking a day wouldn’t matter.

Chemical guides and first-hand experience say tight lids save more money than they cost. Using glass bottles with solid, chemical-resistant stoppers beats old plastic jars. For larger amounts, sealed metal drums with air-tight liners work better, especially in humid climates. Silica gel packets do a solid job inside storage cabinets to keep the air dry.

Oxygen: The Silent Problem

Oxygen in the air acts as a slow-acting enemy. Over time, it nudges the iodide into changing color and properties, sometimes forming copper(II) compounds that stray from what labs or manufacturing lines expect. Storage in a low-oxygen environment matters just as much as keeping out water. In the industry, adding a layer of inert gas like nitrogen inside the container cuts down on this steady damage. Even at home or school labs, filling the container completely or using vacuum-sealed pouches helps.

Light Exposure

Bright light slowly breaks down cuprous iodide, especially sunlight or fluorescent bulbs. Discoloration seems like a harmless cosmetic issue, but in research settings, it skews results and wastes time. Dark, opaque bottles placed in the back of a cupboard win every time over clear plastic sitting under a light fixture.

Temperature Fluctuations Hurt Reliability

Damp basements and outdoor sheds never cut it for chemical storage. High temperatures and swings between cold nights and warm days pull moisture through seals and speed up breakdown. A climate-controlled storage room, or even just a shelf away from vents and sunlight, preserves the right structure and keeps storage headaches away. I worked in a lab where avoiding the HVAC vent meant the difference between clean results and a mess of cross reactions.

Labeling, Segregation, and Safety

Labeling with clear chemical names and hazards cuts through confusion. Storing cuprous iodide separately from strong acids or bases avoids unintended reactions. It sounds like common sense, but in shared workspaces, unlabeled containers or mixed shelves have caused too many close calls. Training staff to notice, label, and fix storage issues goes well beyond regulatory checklists—it reflects whether a lab or facility really puts safety first.

Responsible Handling Pays Off

Cuprous iodide isn’t outrageously hazardous compared to more volatile chemicals, but carelessness invites trouble. Small investments in better containers, old-school labeling, and setting aside dry, dark storage stops most problems before they start. Protection for users, accurate research, and reliable industrial results all start with these simple habits. Proper storage of even the most routine materials, in my experience, always pays off in fewer headaches and a lot more peace of mind.

What are the main properties of Cuprous Iodide?

A Closer Look at the Basics

Cuprous iodide, or copper(I) iodide, comes across as a pretty unassuming white powder at first glance. Touch it, and you’d notice it stiffens up to reddish brown fast if the air's got enough light on it. In plain words, it does not stick around looking pure and white unless kept away from sunlight.

Digging into its makeup, cuprous iodide is a copper compound that pairs copper in a +1 state with iodide ions. It doesn't dissolve in water, which means you won’t get far trying to rinse it down the sink. Toss it in potassium iodide solution, though, and things change—suddenly, it becomes way more willing to dissolve, thanks to complex ions forming in the mixture. This solubility trick makes it easier to work with in labs or in industrial settings where reactions need to get going.

Stability and Behavior

In the real world, cuprous iodide stands up nicely to heat. You can push it past 600 degrees Celsius before it melts. I’ve seen this stability put to use in syntheses that throw a lot of energy into the mix, without the powder breaking apart or reacting in unwanted ways. It also shrugs off most organic solvents, which means it keeps its character even when mixed with other chemicals.

The chemical also likes to play matchmaker—helping other compounds pair up in organic reactions. Chemists turn to it as a trusted catalyst in coupling reactions, including the classic Ullmann reaction that joins two aromatic rings together. These aren’t just lab curiosities; they form the backbone for making medicines, polymers, and photography chemicals.

Uses That Hit Close to Home

Cuprous iodide might not end up in your medicine cabinet, but traces of it reach everyday life. Some countries add it to table salt in tiny amounts to boost daily iodine intake, helping prevent thyroid issues. Not everyone agrees on this use because people argue about absorption rates and potential side effects, but the history is there.

The compound shows up in weather modification efforts, tossed into clouds to encourage rain by acting as a nucleus for water droplets. I find this one of the most fascinating uses—a bit controversial, sure, but it highlights the real-world impact of basic chemical properties. Its ability to provide structure for ice crystals comes straight out of its solid lattice arrangement.

Risks and Solutions

Nothing should go unchecked, and cuprous iodide isn’t flawless. Breathe in too much dust and you risk irritation or toxic symptoms, so any workplace needs solid ventilation and personal protective equipment. Companies sometimes struggle with safe disposal, since copper compounds can build up in soil and aquatic systems, harming life if released unchecked.

I’ve watched companies tackle this by recycling leftover scrap where possible and using strict filtration systems. There’s growing interest in “greener” catalysts, with researchers exploring copper complexes that deliver similar results at lower environmental cost. If those efforts pan out, industries could keep their chemistry clean without trading away efficiency.

Why It Matters

Cuprous iodide’s legacy sits at the intersection of chemistry and everyday experience. It’s a core ingredient for important pharmaceutical, photographic, and agricultural products. Anyone working with it, from lab techs to industrial producers, has a stake in understanding not just its properties, but also its quirks and limitations. Choices about sourcing, handling, and long-term impact start from knowing exactly what makes this chemical tick.

Cuprous Iodide
Cuprous Iodide
Cuprous Iodide
Names
Preferred IUPAC name Copper(I) iodide
Other names Copper(I) iodide
Cuprous iodide
Copper monoiodide
Iodocuprate
Pronunciation /ˈkjuːprəs ˈaɪəˌdaɪd/
Identifiers
CAS Number 7758-05-6
Beilstein Reference 3589928
ChEBI CHEBI:31348
ChEMBL CHEMBL1223038
ChemSpider 20738421
DrugBank DB11167
ECHA InfoCard 03a7331c-e6e4-44a8-8288-1c6fd65f6d89
EC Number 231-674-6
Gmelin Reference 170411
KEGG C18874
MeSH D003556
PubChem CID 24602
RTECS number U42809
UNII F95A5L0V7J
UN number UN3077
CompTox Dashboard (EPA) Q420409
Properties
Chemical formula CuI
Molar mass 190.45 g/mol
Appearance White to tan powder
Odor Odorless
Density DENSITY: 5.62 g/mL at 25 °C
Solubility in water poorly soluble
log P -6.57
Vapor pressure Negligible
Basicity (pKb) 13.6
Magnetic susceptibility (χ) −47.7·10⁻⁶ cm³/mol
Refractive index (nD) 2.19
Dipole moment 0 D
Thermochemistry
Std molar entropy (S⦵298) 77.6 J⋅mol⁻¹⋅K⁻¹
Std enthalpy of formation (ΔfH⦵298) -138.0 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -147.2 kJ/mol
Pharmacology
ATC code V03AK03
Hazards
Main hazards Toxic if swallowed, causes skin irritation, causes serious eye irritation.
GHS labelling GHS02, GHS07
Pictograms GHS07,GHS09
Signal word Warning
Hazard statements H410: Very toxic to aquatic life with long lasting effects.
Precautionary statements Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
NFPA 704 (fire diamond) 2-0-0
Lethal dose or concentration LD50 (oral, rat): 206 mg/kg
LD50 (median dose) LD50 (median dose) of Cuprous Iodide: 1200 mg/kg (oral, rat)
NIOSH CY9280000
PEL (Permissible) 0.1 mg/m3
REL (Recommended) 1 mg/L
IDLH (Immediate danger) IDLH: 500 mg/m³
Related compounds
Related compounds Copper(I) chloride
Copper(I) bromide
Copper(II) iodide
Silver iodide